Number of extractionsin determination of effective cation-exchange capacity

Authors

• Raina Niskanen University of Helsinki, Department of Agricultural Chemistry, SF-00710 HELSINKI, Finland

DOI: https://doi.org/10.23986/afsci.72220

Abstract

The number of successive extractions with 1 M KCI needed for adequate estimation of effective cation-exchange capacity was studied with four mineral soils. The effective CEC estimated as the sum of equivalents of exchangeable Ca, Mg, Na, H and Al extracted by four successive treatments ranged from 57 to 206 meq/kg soil. In three cultivated soils, 63—90 % of CEC was saturated by Ca and Mg, in the fourth soil (a deeper layer virgin soil), 60 % of CEC by exchangeable H and Al. By two successive treatments often minutes duration with 50ml of 1 M KCI, the equivalent sum of exchangeable cations extracted amounted to 83—92 % of effective CEC in cultivated soils and 67 % of that in virgin soil; >90 % of exchangeable Ca and Mg, 78—97 % of Al, 48—62 % of H and 28—64 % of Na were extracted. By three successive treatments the equivalent sum amounted to 79—96 % of effective CEC, by the single treatment of 30 minutes duration with 100ml of 1 M KCI to 57—79 %. Two successive extractions with 1 M KCI may be enough for estimation of effective CEC in cultivated mineral soils with high degree of saturation by exchangeable Ca and Mg. Soils with high degree of saturation by exchangeable acidity require three successive extractions.