Sulphate sorption by Finnish mineral soils

Authors

• Markku Yli-Halla Kemira Oy, Espoo Research Centre, Luoteisrinne 2 SF-02270 ESPOO, Finland

DOI: https://doi.org/10.23986/afsci.72245

Abstract

Sulphate sorption by 38 Finnish cultivated mineral soils was determined and its correlation with soil properties was studied. Sulphate sorption was correlated with soil pH (r =—0.46**) and with phosphate sorption (r =0.69***). With increasing soil pH, sulphate sorption decreased in relation to phosphate sorption. Phosphorus status was decisive in explaining the sulphate sorption of the soils. Even if both anions are sorbed by the same soil component (amorphous Al compounds), the sites are not available for sulphate if they are already occupied by phosphate. Sulphate sorption was negligible in soils very rich in easily soluble phosphorus. This was reflected in a close negative correlation between sulphate sorption and acid ammonium acetate (pH 4.65) extractable phosphorus (r =—0.70***). During the last few decades, phosphorus fertilization has increased the amount of easily soluble phosphorus in Finnish fields, which obviously has decreased the capacity of the soils to retain sulphate.